4-Methyl-N-(4-nitrobenzoyl)benzenesulfonamide
نویسندگان
چکیده
In title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 81.5 (2)° and that between the sulfonyl and the benzoyl benzene rings is 89.8 (1)°. In the crystal, mol-ecules are linked into chains along the b axis via inter-molecular N-H⋯O hydrogen bonds. C-H⋯O inter-actions are also observed.
منابع مشابه
2-Methyl-N-(4-nitrobenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)N(2)O(5)S, the conformation of the N-C bond in the C-SO(2)-NH-C(O) segment has gauche torsions with respect to the S=O bonds. The mol-ecule is twisted at the S atom, the C-S(O(2))-NH-C(O) torsion angle being 61.8 (5)°. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 86.8 (2)° and that between the sulfonyl and the benzoyl ben...
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In the title compound, C(13)H(9)ClN(2)O(5)S, the N-H bond is trans to the C=O bond. The dihedral angle between the two aromatic rings is 85.4 (1)°. In the crystal, mol-ecules are linked into zigzag C(4) chains along the b axis through N-H⋯O hydrogen bonds.
متن کامل4-Chloro-N-(4-nitrobenzoyl)benzenesulfonamide
In the crystal structure of the title compound, C(13)H(9)ClN(2)O(5)S, the N-H bond is trans to the C=O bond (H-N-C-O torsion angle = 158.4°). The dihedral angle between the two aromatic rings is 87.8 (1)°. In the crystal, mol-ecules are linked into chains along the b axis via N-H⋯O hydrogen bonds.
متن کاملN-(3-Methylphenyl)-N′-(4-nitrobenzoyl)thiourea
Two mol-ecules of the title compound, C(15)H(13)N(3)O(3)S, are linked by an inter-molecular N-H⋯S hydrogen bond. There is also an intra-molecular N-H⋯O hydrogen bond, forming a six-membered ring. The steric restriction of the m-methyl and p-nitro groups, as well as the intra-molecular hydrogen bond, are the main factors influencing the mol-ecular conformation.
متن کاملN-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide
In the title compound, C(22)H(23)NO(4)S(2), the dihedral angles between the dimethyl-phenyl ring and the two methyl-phenyl rings are 41.19 (15) and 20.50 (17)°; the dihedral angle between the methyl-phenyl rings is 48.11 (14)°. The C-N-S-C torsion angles are -87.6 (2) and 77.43 (18)°. The only possible directional inter-actions in the crystal are very weak C-H⋯π inter-actions and very weak π-π ...
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